(S)-Garner aldehyde
tert-butyl (S)-(-)-4-formyl-2,2-dimethyl-3-oxazol
CAS: 102308-32-7
Molecular Formula: C11H19NO4
(S)-Garner aldehyde - Names and Identifiers
(S)-Garner aldehyde - Physico-chemical Properties
| Molecular Formula | C11H19NO4 |
| Molar Mass | 229.27 |
| Density | 1.06g/mLat 25°C(lit.) |
| Boling Point | 83-88°C1mm Hg(lit.) |
| Specific Rotation(α) | D -91.7° (c = 1.34 in CHCl3) |
| Flash Point | 226°F |
| Water Solubility | Slightly soluble in water. |
| Solubility | Chloroform (Slightly), Methanol (Slightly) |
| Vapor Presure | 0.001mmHg at 25°C |
| Appearance | Transparent colorless to yellow oily |
| Color | Clear colorless to yellow |
| BRN | 3591324 |
| pKa | -3.26±0.60(Predicted) |
| Storage Condition | Inert atmosphere,2-8°C |
| Sensitive | Air Sensitive |
| Refractive Index | n20/D 1.445(lit.) |
| MDL | MFCD00209557 |
| Use | This product is for scientific research only and shall not be used for other purposes. |
(S)-Garner aldehyde - Risk and Safety
| Hazard Symbols | Xi - Irritant |
| Risk Codes | 36/37/38 - Irritating to eyes, respiratory system and skin. |
| Safety Description | S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S36 - Wear suitable protective clothing. S37/39 - Wear suitable gloves and eye/face protection |
| WGK Germany | 3 |
| HS Code | 29349990 |
(S)-Garner aldehyde - Reference Information
| Introduction | 3-trans-bromocarbon -2,2 '-dimethyloxate is transparent colorless to yellow oil and can be used as an intermediate in organic synthesis for organic experimental synthesis. |
| Synthesis method | Using L-serine as the starting material, Garner aldehyde is prepared by Boc protection, namely 3-trans-bromocarbon -2,2 '-Dimethyloxate. The synthesis reaction formula of 3-trans-bromocarbon -2,2 '-dimethyloxylate is as follows: |
| use | is widely used in asymmetric synthesis of natural products. |
Last Update：2024-04-09 21:11:58
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